Item type |
紀要論文(ELS) / Departmental Bulletin Paper(1) |
公開日 |
1985-03-05 |
タイトル |
|
|
タイトル |
Chemical Modification of Carbohydrates through Reaction with Organometallic Agents |
|
言語 |
ja |
タイトル |
|
|
タイトル |
Chemical Modification of Carbohydrates through Reaction with Organometallic Agents |
|
言語 |
en |
言語 |
|
|
言語 |
eng |
資源タイプ |
|
|
資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
|
資源タイプ |
departmental bulletin paper |
ページ属性 |
|
|
内容記述タイプ |
Other |
|
内容記述 |
P(論文) |
著者名 |
直島, 好信
黒川, 正英
広野, 里美
Charles E.Carraher, Jr.
George G.Hess
|
著者所属(日) |
|
|
|
ja |
|
|
岡山理科大学化学科 |
著者所属(日) |
|
|
|
ja |
|
|
岡山理科大学化学科 |
著者所属(日) |
|
|
|
ja |
|
|
岡山理科大学化学科 |
著者所属(日) |
|
|
|
ja |
|
|
ライト大学化学科 |
著者所属(日) |
|
|
|
ja |
|
|
ライト大学化学科 |
著者所属(英) |
|
|
|
en |
|
|
Department of Chemistry,Okayama University of Science |
著者所属(英) |
|
|
|
en |
|
|
Department of Chemistry,Okayama University of Science |
著者所属(英) |
|
|
|
en |
|
|
Department of Chemistry,Okayama University of Science |
著者所属(英) |
|
|
|
en |
|
|
Department of Chemistry,Wright State University |
著者所属(英) |
|
|
|
en |
|
|
Department of Chemistry,Wright State University |
抄録(英) |
|
|
内容記述タイプ |
Other |
|
内容記述 |
Intimate, homogeneous modification of two polyhydroxylic polysaccharides derived from both of cotton (1) and dextran (2) has been studied through reaction with a wide variety of organometallic reactants. Cotton (1), a water insoluble, cellulosic polysaccharide, was treated with a variety of organotin halides in the presence of bis (ethylenediamine) copper(II) hydroxide as both solvent and added base using an interfacial condensation system. Dextran (2), a water soluble polysaccharide, was modified through condensation with both organotin and organotitanium halides employing sodium hydroxide and/or triethylamine as the added base. Analysis of both condensation products indicated the presence of tin or titanium in the crosslinked lattice of the polysaccharide. The product is a combination of a number of modified structure units linked to each other or to unmodified saccharide units. In addition, sucrose (3), which is a naturally occurring disaccharide, was successfully polymerized through reaction with a number of organotin dihalides employing the aqueous interfacial condensation technique to form crosslinked networks. |
|
言語 |
en |
雑誌書誌ID |
|
|
収録物識別子タイプ |
NCID |
|
収録物識別子 |
AN00033244 |
書誌情報 |
ja : 岡山理科大学紀要. A, 自然科学
en : The Bulletin of the Okayama University of Science, A, Natural Science
巻 20,
p. 33-41,
発行日 1985-03-05
|