{"created":"2023-06-19T10:34:35.313992+00:00","id":433,"links":{},"metadata":{"_buckets":{"deposit":"48824ee8-32d3-4136-a84b-338938594284"},"_deposit":{"created_by":14,"id":"433","owners":[14],"pid":{"revision_id":0,"type":"depid","value":"433"},"status":"published"},"_oai":{"id":"oai:ous.repo.nii.ac.jp:00000433","sets":["296:297:305"]},"author_link":["17400","17401","17402"],"item_1_biblio_info_14":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1972-12-25","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"116","bibliographicPageStart":"109","bibliographicVolumeNumber":"8","bibliographic_titles":[{"bibliographic_title":"岡山理科大学紀要","bibliographic_titleLang":"ja"},{"bibliographic_title":"Bulletine of Okayama University of Science","bibliographic_titleLang":"en"}]}]},"item_1_creator_6":{"attribute_name":"著者名","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"圓堂, 稔","creatorNameLang":"ja"},{"creatorName":"エンドウ, ミノル","creatorNameLang":"ja-Kana"},{"creatorName":"Endoh, Minoru","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"17400","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"土井, 章","creatorNameLang":"ja"},{"creatorName":"ドイ, アキラ","creatorNameLang":"ja-Kana"},{"creatorName":"Doi, Akira","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"17401","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"加藤, 忠蔵","creatorNameLang":"ja"},{"creatorName":"カトウ, チュウゾウ","creatorNameLang":"ja-Kana"},{"creatorName":"Kato, Chuzo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"17402","nameIdentifierScheme":"WEKO"}]}]},"item_1_description_1":{"attribute_name":"ページ属性","attribute_value_mlt":[{"subitem_description":"P(論文)","subitem_description_type":"Other"}]},"item_1_description_11":{"attribute_name":"抄録(日)","attribute_value_mlt":[{"subitem_description":"CuOの種々の性質については調べられているが熱分解過程に関する報告はまだなされていない.本研究ではCuOの熱分解過程におけるCuOの熱特性についてAir, CO_2,N_2中のDTAを基にして, TG, X-ray, 顕微鏡観察, 表面積測定等により考察した.試料として用いたCuOは調製したCu(OH)_2を粉末とし加熱処理しN_2雰囲気下にて放冷したものを使用した.熱特性について1200℃まで研究した結果CuOのDTA曲線には400°～900℃の間に発熱ピークが現われ, この発熱ピークはCO_2雰囲気下ではより増大し, N_2雰囲気下では消失した.500℃と900℃とにおける比表面積及び粒径を測定した結果, 500℃に比べ900℃における比表面積は1/3に, 粒径は約3倍となり400℃～900℃の間に現われた発熱はCuOの結晶化によるものと思われ, X線分析の結果も同様の傾向を示した.1014℃の吸熱ピークによる生成物はX線分析の結果Cu_2Oである事を確認し, またこのピーク前後で試料の色が黒色から赤色に変色した事からCuOの分解に基因すると思われた.また1106℃においてCu_2Oの融解による吸熱ピークが現われた.この吸熱ピーク直前の1100℃におけるX線分析の結果.Cu_2OとCuOが形成されており, 従ってCu_2Oは融解直前において一部がCuOに酸化されると思われた.DTA曲線の融解による吸熱ピーク直前の発熱ピーク中, TG曲線にわずかな増量が認められ, X線分析の結果を裏づけた.","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_1_source_id_13":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00033233","subitem_source_identifier_type":"NCID"}]},"item_1_text_10":{"attribute_name":"著者所属(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Department of Applied Chemistry, Okayama University of Science"},{"subitem_text_language":"en","subitem_text_value":"Department of Applied Chemistry, Okayama University of Science"},{"subitem_text_language":"en","subitem_text_value":"Department of Applied Chemistry, Waseda University"}]},"item_1_text_9":{"attribute_name":"著者所属(日)","attribute_value_mlt":[{"subitem_text_language":"ja","subitem_text_value":"岡山理科大学応用化学科"},{"subitem_text_language":"ja","subitem_text_value":"岡山理科大学応用化学科"},{"subitem_text_language":"ja","subitem_text_value":"早稲田大学理工学部応用化学科"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"1972-12-25"}],"displaytype":"detail","filename":"KJ00000063152.pdf","filesize":[{"value":"367.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"url":"https://ous.repo.nii.ac.jp/record/433/files/KJ00000063152.pdf"},"version_id":"16c68bf1-1f74-4f27-b5ff-6c9b66817372"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"CuOの熱特性","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"CuOの熱特性","subitem_title_language":"ja"},{"subitem_title":"The Thermal Property of CuO","subitem_title_language":"en"},{"subitem_title":"CUO ノ ネツ トクセイ","subitem_title_language":"ja-Kana"}]},"item_type_id":"1","owner":"14","path":["305"],"pubdate":{"attribute_name":"PubDate","attribute_value":"1972-12-25"},"publish_date":"1972-12-25","publish_status":"0","recid":"433","relation_version_is_last":true,"title":["CuOの熱特性"],"weko_creator_id":"14","weko_shared_id":-1},"updated":"2023-10-04T00:37:10.297889+00:00"}