{"created":"2023-06-19T10:34:33.955075+00:00","id":408,"links":{},"metadata":{"_buckets":{"deposit":"7ed89eb8-5eea-4ee5-b2c0-0da432132454"},"_deposit":{"created_by":14,"id":"408","owners":[14],"pid":{"revision_id":0,"type":"depid","value":"408"},"status":"published"},"_oai":{"id":"oai:ous.repo.nii.ac.jp:00000408","sets":["296:297:304"]},"author_link":["17320","17321"],"item_1_biblio_info_14":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1971-12-25","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"84","bibliographicPageStart":"77","bibliographicVolumeNumber":"7","bibliographic_titles":[{"bibliographic_title":"岡山理科大学紀要","bibliographic_titleLang":"ja"},{"bibliographic_title":"Bulletine of Okayama University of Science","bibliographic_titleLang":"en"}]}]},"item_1_creator_6":{"attribute_name":"著者名","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"江見, 浩一","creatorNameLang":"ja"},{"creatorName":"エミ, コウイチ","creatorNameLang":"ja-Kana"},{"creatorName":"Emi, Koichi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"善木, 道雄","creatorNameLang":"ja"},{"creatorName":"ゼンキ, ミチオ","creatorNameLang":"ja-Kana"},{"creatorName":"Zenki, Michio","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_1_description_1":{"attribute_name":"ページ属性","attribute_value_mlt":[{"subitem_description":"P(論文)","subitem_description_type":"Other"}]},"item_1_description_11":{"attribute_name":"抄録(日)","attribute_value_mlt":[{"subitem_description":"モリブデン(VI)-チロン錯体のゼフィラミン(tetradecyl dimethyl benzyl ammonium chloride)による抽出吸光光度定量法について検討した.弱酸性領域(pH4.6～7.6)でこの錯体は, 1,2-dichloroethaneに抽出され, 400nmに吸収極大を示す.モリブデン(VI)-チロンとの結合比は水溶液層では1 : 1であるが, 有機層中では1 : 2である.抽出によって, 感度は水溶液のそれよりかなりの増加がみとめられ, 最適条件での分子吸光係数は23.000,モリブデン(VI)濃度0～4.3×10^<-5>Mの範囲でベールの法則が成立することをみとめた.また, モリブデン(VI)-チロン-ゼフィラミン錯体の組成比は1 : 2 : 2であった.","subitem_description_language":"ja","subitem_description_type":"Other"}]},"item_1_description_12":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"The extraction of molybdenum (VI)-Tiron complex with quaternary ammonium chloride has beeu investigated for the determination of molybdenum (VI). The complex extracted into 1,2-dichloroethane has an absorption maximum at 400 nm, with a constant absorption in the pH range from 4.6 to 7.6. The molar ratio of molybdenum (VI) to Tiron in the complex is estimated to be 1 to 1 for aqueous phase, and 1 to 2 for organic phase. By extracting into organic phase with tetradecyldimethyl ammonium chloride (Zep), the complex, Mo [(Tiron)_2(Zep)_2], whose molar absorptivity is 23,000 at 400nm is formed. Beer's Law is obeyed within the limits of 0～4.3×10^<-3>M.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_1_source_id_13":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00033233","subitem_source_identifier_type":"NCID"}]},"item_1_text_9":{"attribute_name":"著者所属(日)","attribute_value_mlt":[{"subitem_text_language":"ja","subitem_text_value":"岡山理科大学"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"1971-12-25"}],"displaytype":"detail","filename":"KJ00000063127.pdf","filesize":[{"value":"316.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"url":"https://ous.repo.nii.ac.jp/record/408/files/KJ00000063127.pdf"},"version_id":"ddbf75fd-f86a-422d-bcc3-1c86df894629"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"第4級アンモニウム塩によるモリブデン(VI)-チロン錯体の抽出およびこれを利用したモリブデン(VI)の吸光光度定量","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"第4級アンモニウム塩によるモリブデン(VI)-チロン錯体の抽出およびこれを利用したモリブデン(VI)の吸光光度定量","subitem_title_language":"ja"},{"subitem_title":"Spectrophotometric determination of molybdenum(VI) by extracting of molybdenum(VI)-Tiron complex with quaternary ammonium chloride","subitem_title_language":"en"},{"subitem_title":"ダイ4キュウ アンモニウム エン ニヨル モリブデン 6 チロン サクタイ ノ チュウシュツ オヨビ コレオ リヨウ シタ モリブデン 6 ノ キュウコウ コウド テイリョウ","subitem_title_language":"ja-Kana"}]},"item_type_id":"1","owner":"14","path":["304"],"pubdate":{"attribute_name":"PubDate","attribute_value":"1971-12-25"},"publish_date":"1971-12-25","publish_status":"0","recid":"408","relation_version_is_last":true,"title":["第4級アンモニウム塩によるモリブデン(VI)-チロン錯体の抽出およびこれを利用したモリブデン(VI)の吸光光度定量"],"weko_creator_id":"14","weko_shared_id":-1},"updated":"2023-09-27T02:55:11.497530+00:00"}