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Spectrophotometric Determination of Aluminium with Salicylidene-o-aminophenol-4-sulfonic Acid
https://ous.repo.nii.ac.jp/records/615
https://ous.repo.nii.ac.jp/records/615587a0fb0-9130-425f-85d5-5cedb25328b8
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KJ00000063031.pdf (202.9 kB)
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| Item type | 紀要論文(ELS) / Departmental Bulletin Paper(1) | |||||||||||||||||
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| 公開日 | 1981-03-05 | |||||||||||||||||
| タイトル | ||||||||||||||||||
| タイトル | Spectrophotometric Determination of Aluminium with Salicylidene-o-aminophenol-4-sulfonic Acid | |||||||||||||||||
| 言語 | ja | |||||||||||||||||
| タイトル | ||||||||||||||||||
| タイトル | Spectrophotometric Determination of Aluminium with Salicylidene-o-aminophenol-4-sulfonic Acid | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| 言語 | ||||||||||||||||||
| 言語 | eng | |||||||||||||||||
| 資源タイプ | ||||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||
| 資源タイプ | departmental bulletin paper | |||||||||||||||||
| ページ属性 | ||||||||||||||||||
| 内容記述タイプ | Other | |||||||||||||||||
| 内容記述 | P(論文) | |||||||||||||||||
| 著者名 |
善木, 道雄
× 善木, 道雄
× 堀, 和子
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| 著者所属(日) | ||||||||||||||||||
| ja | ||||||||||||||||||
| 岡山理科大学化学科 | ||||||||||||||||||
| 著者所属(日) | ||||||||||||||||||
| ja | ||||||||||||||||||
| 岡山理科大学化学科 | ||||||||||||||||||
| 著者所属(英) | ||||||||||||||||||
| en | ||||||||||||||||||
| Department of Chemistry, Okayama University of Science | ||||||||||||||||||
| 著者所属(英) | ||||||||||||||||||
| en | ||||||||||||||||||
| Department of Chemistry, Okayama University of Science | ||||||||||||||||||
| 抄録(英) | ||||||||||||||||||
| 内容記述タイプ | Other | |||||||||||||||||
| 内容記述 | Salicylidene-o-aminophenol (SAPH), one of the typical Schiff base, has been studied as a spectrofluorimetric reagent for aluminium and also as a spectro-photometric reagent for copper, cadmium and zinc. As be expected from the structure, SAPH and its metal complexes are insoluble in water, then analytical difficulties result from the formation of the precipitates. Therefore, the methods such as precipitation followed by acid dissolution, solvent extraction or solubilization with quaternary ammonium salt are necessary for the determination. Salicylidene-o-aminophenol-4-sulfonic acid (SAPS), a SAPH derivative which introduced a sulfonic acid group into a phenyl ring, becomes soluble in water. It is available a simple and rapid determination of certain metals without any treatment. Morishige had reported the high sensitivity of SAPS on the fluorescence properties compared with 87 Schiff bases. Fluorimetry is more sensitive than spectrophotometry, but requires a instrumental necessity and skillfulness. The authors proposed the use of SAPS for the spectrophotometry in water solution, and determined copper and vanadium easily. This paper presents that SAPS as a spectrophotometric determination for aluminium and application to the determination of aluminium in steels. | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| 雑誌書誌ID | ||||||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||||||
| 収録物識別子 | AN00033233 | |||||||||||||||||
| 書誌情報 |
ja : 岡山理科大学紀要 en : The Bulletin of the Okayama University of Science, 巻 16, p. 101-105, 発行日 1981-03-05 |
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