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Flash Dehydroxylation of Montmorillonite
https://ous.repo.nii.ac.jp/records/392
https://ous.repo.nii.ac.jp/records/3926b98647c-bad5-400c-9b58-c51ab003db19
名前 / ファイル | ライセンス | アクション |
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Item type | 紀要論文(ELS) / Departmental Bulletin Paper(1) | |||||||||||||||||
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公開日 | 1970-12-25 | |||||||||||||||||
タイトル | ||||||||||||||||||
タイトル | Flash Dehydroxylation of Montmorillonite | |||||||||||||||||
言語 | ja | |||||||||||||||||
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タイトル | Flash Dehydroxylation of Montmorillonite | |||||||||||||||||
言語 | en | |||||||||||||||||
言語 | ||||||||||||||||||
言語 | eng | |||||||||||||||||
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資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||
資源タイプ | departmental bulletin paper | |||||||||||||||||
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内容記述タイプ | Other | |||||||||||||||||
内容記述 | P(論文) | |||||||||||||||||
著者名 |
土井, 章
× 土井, 章
× 加藤, 忠蔵
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著者所属(日) | ||||||||||||||||||
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岡山理科大学応用化学科 | ||||||||||||||||||
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ja | ||||||||||||||||||
早稲田大学応用化学科 | ||||||||||||||||||
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en | ||||||||||||||||||
Department of Applied Chemistry, Okayama University of Science | ||||||||||||||||||
著者所属(英) | ||||||||||||||||||
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Department of Applied Chemistry, Waseda University | ||||||||||||||||||
抄録(英) | ||||||||||||||||||
内容記述タイプ | Other | |||||||||||||||||
内容記述 | The effect of flash decrease of pressure on the dehydroxylation process of montmorillonite (Yamagata Prefecture, Japan) was studied. The experimental technique based on flash dehydroxylation means that the sample under atmospheric pressure was transferred to vacuum in a moment. The properties of flash dehydroxylation sample and the heating samples under constant pressure were investigated by means of X-ray, DTA, TG, and IR, etc.. The dehydroxylation temperature of lattice water was shifted to lower temperature with the decreasing pressure. The time for diffusion process of water molecules accompanied with dehydroxylation was rapidly redued below 100 mmHg. The basal spacing of two heating samples under constant pressure gave 9.73A and that of flash dehydroxylation sample gave 9.60A. The gap of 0.13A might depend on the different shift of potassium ion situated between the crystal layer. Namely, the exchangeable cation which occupied the space between the crystal sheets just before dehydroxylation shifted into vacant space in silicon-oxygen sheet which had come from dehydroxylation by means of flash pressure change. New pattern of 20-26A were appeared in X-ray diffraction of flash dehydroxylation samples prepared by alkali-treatment. The influence of the water molecules diffusion on crystal structure of montmorillonite might be minimized by flash change of pressure. | |||||||||||||||||
言語 | en | |||||||||||||||||
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収録物識別子タイプ | NCID | |||||||||||||||||
収録物識別子 | AN00033233 | |||||||||||||||||
書誌情報 |
ja : 岡山理科大学紀要 en : Bulletine of Okayama University of Science 巻 6, p. 119-126, 発行日 1970-12-25 |